A new approach to the ring opening reactions of 2,7,7-trimethyl-3,3- dibromotricyclo[4.1.1.02,4]octane
Turkish Journal of Chemistry, cilt.29, sa.5, ss.531-538, 2005 (SCI-Expanded, Scopus, TRDizin)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 29 Sayı: 5
- Basım Tarihi: 2005
- Dergi Adı: Turkish Journal of Chemistry
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, TR DİZİN (ULAKBİM)
- Sayfa Sayıları: ss.531-538
- Trakya Üniversitesi Adresli: Evet
Özet
The reaction of α-pinene and dibromocarbene produced a fairly unstable product, 2,7,7-trimethyl3,3-dibromotricyclo[4.1.1.02,4] octane, from which 3-bromo-7,7-dimethyl-2-methylenebicyclo[4,1,1]oct-3-ene and 3-bromo-2,7,7-trimethylbicyclo [4,1,1]octa-2,4-diene were obtained in chloroform at room temperature and in various other media and conditions. Two new compounds, 3-bromo-2,7,7-trimethylbicyclo [4.1.1]oct-3-en-2-ol and 2-(4-bromo-5-methylcyclohepta-3,5-dien-1-yl) propan-2-ol, were observed in aqueous acetone in addition to the previous two. The stability and formation mechanism of the formed products are discussed. © TÜBİTAK.