A mild, aromatization of cyclic compounds and oxidation of amino groups to carbonyls using o-iodoxybenzoic acid

KAÇAN M., ÇİÇEK G., KARABULUT H., ÖZYILDIRIM H.

Asian Journal of Chemistry, cilt.25, sa.13, ss.7649-7650, 2013 (SCI-Expanded, Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 25 Sayı: 13
  • Basım Tarihi: 2013
  • Doi Numarası: 10.14233/ajchem.2013.15129
  • Dergi Adı: Asian Journal of Chemistry
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.7649-7650
  • Anahtar Kelimeler: Aromatization, N-Cyclohexylaniline, O-Iodoxybenzoic acid, Oxidation
  • Trakya Üniversitesi Adresli: Evet

Özet

A new, mild and efficient method has been developed for the synthesis of aromatic compounds and some carbonyls via the oxidative aromatization of amino cyclic compound by using hypervalent iodine reagent in DMSO at ambient temperature. The facile synthetic accessibility and it is as mild as non-hazardous nature render o-iodoxybenzoic acid equivalent of Dess-Martin periodinane reagent in organic oxidations.