New picrotoxane terpenoids, austrobuxusin A-D, from the Australian endemic plant Austrobuxus swanii

DEMİRKIRAN Ö., Campitelli M., Wang C., Feng Y.

Tetrahedron, cilt.72, sa.51, ss.8400-8405, 2016 (SCI-Expanded, Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 72 Sayı: 51
  • Basım Tarihi: 2016
  • Doi Numarası: 10.1016/j.tet.2016.10.061
  • Dergi Adı: Tetrahedron
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.8400-8405
  • Anahtar Kelimeler: Austrobuxus, Picrodendron, Picrotoxane terpenoids
  • Trakya Üniversitesi Adresli: Evet

Özet

Four new picrotoxane terpenoids, austrobuxusin A–D (1–4), were isolated from the Australian endemic plant Austrobuxus swanii. Their structures were fully characterized by 1D- and 2D-NMR and MS data. The relative configurations of compounds (1–4) were assigned by phase-sensitive ROESY experiment. The absolute configuration of austrobuxusin A (1) was determined by the comparison of experimental and DFT-calculated CD spectra. This is the first report of picrotoxane terpenoids from the Australian plant Austrobuxus swanii.