Application of IBX Method for the Synthesis of Ketones from Carboxylic Acids

KARABULUT H., KAÇAN M., ÖZYILDIRIM H.

Turkish Journal of Chemistry, cilt.27, sa.6, ss.713-716, 2003 (SCI-Expanded, Scopus, TRDizin) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 27 Sayı: 6
  • Basım Tarihi: 2003
  • Dergi Adı: Turkish Journal of Chemistry
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, TR DİZİN (ULAKBİM)
  • Sayfa Sayıları: ss.713-716
  • Anahtar Kelimeler: IBX (o-iodoxy benzoic acid), Ketone, Methoxy phenyl propionic acid, Oxidation
  • Trakya Üniversitesi Adresli: Evet

Özet

Methoxy phenyl propionic acid and some derivatives are converted to ketones using a new method. All classical methods to obtain ketones from carboxylic acids via acid halide consistently gave very low yields and regularly generated intermolecular cyclisation products or polymeric materials. However, high ketones yields are obtained by using the new IBX method.